Enols (also known as alkenols) are alkenes with a hydroxyl group affixed to one of the carbon atoms composing the double bond. Enols and carbonyl compounds (such as ketones and aldehydes) are in fact isomers; this is called keto-enol tautomerism: The enol form is shown above on the left. It is usually unstable, doesn't survive long, and changes into the keto (ketone) form shown on the right. This is because oxygen is more electronegative than carbon and thus forms stronger multiple bonds. Hence,… (More on Enolate) |